Miscibility and isothermal crystallization behavior of polyamide 6/poly(vinyl alcohol) blend

An investigation of miscibility and isothermal crystallization behavior of Polyamide 6 (PA6)/Poly(vinyl alcohol) (PVA) blends was conducted. Fourier transform infrared spectra (FTIR) analysis indicated that the interactions between the carbonyl groups of PA6 and hydroxyl groups of PVA increase as the weight ratios of PA6 to PVA of PA6/PVA specimens increase. This interaction between PA6 and PVA leads to their miscibility in the amorphous region and even some extent effects on their crystal phase, respectively. Further isothermal crystallization behavior of PA6/PVA indicate that the miscibility of PVA in PA6 leading difficulty in crystallization of PA6. Several kinetics equations are employed to describe the effects of PVA on the crystallization properties of PA6 in PA6/PVA blends in detail. © 2008 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 46: 1360–1368, 2008     

STUDIES ON RESPONSE CHARACTERISTICS OF DRUG ISE''''S (Ⅳ) SELECTIVITY OF, DRUG ISE''''S WITH HETERO-POLY ACID ANION SITE TOWARD METAL IONS

The relationship between the selectivity of six drug ion-selective electrodes with anionic species of hetero-poly acid as exchange site and the structural and thermodynamical parameters of the metal ion has been investigated experimentally and theoretically. The electrode selectivity is controlled mainly by the extractibility or hydrophobicity of the metal ion, but not by the ion-association-complex formation process. Linear relationship exists between the pK_(ij) value and the structural parameter z~2/(r + 0.85) and the thermodynamic parameter of hydration (△G_h) of the metal ion. Better correlation is obtained for the pK_(ij)vs. (z~2/r)~(-k) relationship.     

一类对应于高阶微分算子的位势函数

本文针对 Hinz引入的一类位势函数 ,给出了一种对应于高阶微分算子的推广形式 ,并研究了其若干基本性质     

变系数非线性二阶周期边值问题的正解

利用锥上的不动点指数定理考察了变系数非线性二阶周期边值问题的正解.主要定理表明,只要非线性项在某些有界集合上的增长速度是适当的,该问题就具有n个正周期解,其中竹是-个任意的自然数.     

激光场的空间非均匀性对阈上离化的影响

本文在基本态模型中计及激光场的空间非均匀性,得到了与实验相吻合的结果.     

Synthesis and biological evaluation of a new series of histone deacetylases inhibitors

Histone deacetylases （HDACs） play an important role in tumorigenesis. Inhibition of HDACs is considered as a potent strategy for cancer therapy. Two lead compounds （ja and jb） were found to have activities against HDACs with IC50 at about 15 μmol/L. Then a new series of hydroximic acid derivatives were designed and synthesized based on them. The HDACs activity assay in vitro found that compounds J04 and ,109 are nearly as potent as the positive control drug Zolinza.     

煤炭城市可持续发展的系统动力学模拟与调控

煤炭城市是由人口、资源、经济与环境四个子系统构成的复杂系统.其可持续发展依赖于各子系统的合理结构和发展模式以及对系统的有效控制.将可持续发展思想与系统动力学模拟方法相结合,在分析了煤炭城市系统结构基础上,构建了煤炭城市系统动力学模型:确定生育指数、各产业投资比例、资源循环利用率等为调控参数,以典型煤炭城市鸡西市为例进行了5种发展模式的模拟和调控.结果表明:可持续发展模式与其他四种发展模式相比,取得的经济、资源、环境整体效益最大,是鸡西市发展的相对最佳方案.     

物流客户服务水平的综合评价研究

本文在客户问卷调查的基础上,结合国外有关的物流企业客户服务指标,建立了物流客户服务水平评价的指标体系,同时应用定性与定量分析相结合的方法,建立了属性综合评价的物流客户服务水平评价模型,并给出了具体的应用实例.